Concentration of Charges
Equation
If there is more than one type of ion, the actual concentration of the ions must be estimated, that is, add the concentrations weighted by the number of charges they have
$c_m=\sum_i\mid z_i\mid c_i$ |
where
ID:(3883, 0)
Concentration of Charges (1)
Equation
In case of a type of load
$ c_m =\mid z_1 \mid c_1 $ |
where
ID:(3884, 0)
Concentration of Charges (2)
Equation
In case of two types of charges
$ c_m = \mid z_1\mid c_1 + \mid z_2\mid c_2 $ |
where
ID:(3885, 0)
Concentration of Charges (3)
Equation
In case of three types of charges
$ c_m = \mid z_1\mid c_1 + \mid z_2\mid c_2 + \mid z_3\mid c_3 $ |
where
ID:(3886, 0)
Conductivity
Equation
In the case of ion conduction, conductivity must include the sign of the charge, which is entered with the number of charges
$ \kappa =\displaystyle\frac{ z }{ \mid z \mid } \mu_e c $ |
where
ID:(3876, 0)
Equilibrium Condition
Equation
The equilibrium condition occurs when the flow due to the potential difference is equal to the flow due to the diffusion. That is why you have to
for what you have
$ dV =\displaystyle\frac{ R T }{ z F }\displaystyle\frac{ dc }{ c }$ |
ID:(3880, 0)
Fick's Law for Charged Particles
Equation
The diffusion leads to the difference in concentrations
$ j =- D \displaystyle\frac{ dc }{ dx }$ |
where
ID:(3878, 0)
Current density
Equation
The flow density
$ j =\displaystyle\frac{ I }{ S }$ |
ID:(3221, 0)
Concentration Differenz
Equation
The difference in concentration $c_1$ and $c_2$ at the ends of the membrane results in the difference:
$dc=c_2-c_1$ |
ID:(3882, 0)
Diffusion Constant for Charged Particles
Equation
The diffusion constant
$ D =\displaystyle\frac{ \mu_e R T }{\mid z \mid F }$ |
ID:(3879, 0)
Ohm's law with Conductivity
Equation
If a potential difference
so with
y
with what
$ j =- \kappa \displaystyle\frac{ dV }{ dx }$ |
ID:(3877, 0)
Nernst Current
Equation
The electron current is the
that is
equation/druyd>
ID:(3222, 0)
Nernst Potential
Equation
If the potential difference is integrated, the relationship of the potential difference corresponding to the limit in which the electric field is compensated with the Diffusion can be established:
$ V_m =-\displaystyle\frac{ R T }{ F }\ln\displaystyle\frac{ c_1 }{ c_2 }$ |
where
ID:(3881, 0)